Whisper had some good advice...start with just the bar if you're not comfortable with the form, and work your way up. I STILL do this when I switch from normal bench press to incline/decline. If you're starting out, looks like a good all-around full body workout..and if you don't like the standing barbell row, don't be afraid to switch to standing dumbbell rows...I prefer them anyways, as I can target the sides better for some reason. If you want, you can try straight-legged deadlifts for your second day instead of normal deadlifts- that way you're not hitting the quads both days, and straight-legged deadlifts target the glutes and lower back and can include the core more.
As for isolation movements, I would add a few in where you want to progress more, or you need some weak point training (but you won't know that until you get a few months into your workouts at least, so for now I'd focus on what I would want to develop a little more). I started by doing concentration curls since I wanted bigger biceps, and although with correct form barbell curls can be considered an isolation movement, starting out you tend to use your back and shoulders sometimes, whereas when I do concentration curls it's MUCH harder to incorporate the shoulders and back.
Anyways, I hope this can help you...there are ALWAYS alternatives if you don't feel comfortable with a certain exercise, but it's good to still keep a few of what I call "Staple" exercises (squats, bench press, and rows would be considered some. I never liked deadlifting since I can target the same muscle groups with squats and other exercises I prefer).